I wish we got more with Thor and Balck Widow because it's ashamed they never got a lot of screen time together in between their Avengers work.
I know Thor was dealing with the Dark Elves and with Banner and loki in Ragnarok, but I wish we got more time with him and Natasha because she's only one on the OG 6 you never got any sceen time together as friends and co-workers maybe chat about how different upbringings, having different siblings relationships, and maybe form a silent bond with team ups and maybe he show her asgard, pre Ragnarok and maybe talk about the difference with Godhood and humanity. Also, ScarJo and Hemsworth would have great chemistry together even without the other Avengers members. It's opportunity in the infinty saga that i would love to see explore.
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More slice of life stuff on screen, like the party in AoU, would have been delightful, but for pacing and runtime reasons I understand why we didn't get much.
The other problem with Thor, of course, is that the MCU didn't quite know what to do with him, and although Taika Waititi came up with the brilliant (but obvious, really) idea that Thor should always be the coolest character in his own movies and not play second fiddle to Loki, Taika took it too far and gave us the MCU's worst movie in Love and Thunder. Arguably he took it a bit too far in a couple of scenes in Ragnarok too. So now it seems that Marvel is giving us a new version of Thor yet again in Doomsday. Meanwhile all of the other core Avengers have had compete character arcs and are recognizable, consistent characters. I think it's time for Marvel to move on from Thor. He's not a failure the way a character like Captain Marvel is--his movies made respectable money and he works as part of the Avengers ensemble--but he's nowhere near as successful a character as Cap, Nat, Tony or even Clint.
Old Mitchel and Webb sketch. Shows what happens when you pair two heroes of *vastly* different power levels
*"He killed 80 people in 2 days."*
*"He's adopted."*
*"Thor, report on the Hulk."*
*"The gates of Hel are filled with the screams of his victims."*
*"But not the screams of the dead, of course. No, no... wounded screams... mainly whimpering, a great deal of complaining and tales of sprained deltoids and... gout."*
Although it's implied he spent a significant chunk of time with the team between Dark World and Age of Ultron but unfortunately we don't see any of that.